Recent Publications

How non-equilibrium aerosol chemistry impacts particle acidity: the GMXe AERosol CHEMistry (GMXe–AERCHEM, v1.0) sub-submodel of MESSy

How non-equilibrium aerosol chemistry impacts particle acidity: the GMXe AERosol CHEMistry (GMXe–AERCHEM, v1.0) sub-submodel of MESSy

Aqueous-phase chemical processes in clouds, fog, and deliquescent aerosols are known to alter atmospheric composition and acidity significantly. Traditionally, global and regional models predict aerosol composition by relying on thermodynamic equilibrium models and neglect non-equilibrium processes.

Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene

Application of fuzzy c-means clustering for analysis of chemical ionization mass spectra: insights into the gas phase chemistry of NO3-initiated oxidation of isoprene

Oxidation of volatile organic compounds (VOCs) can lead to the formation of secondary organic aerosol (SOA), a significant component of atmospheric fine particles, which can affect air quality, human health, and climate change. However, the current understanding of the formation mechanism of SOA is still incomplete, which is not only due to the complexity of the chemistry but also relates to analytical challenges in SOA precursor detection and quantification.

Quantum yields of CHDO above 300 nm

Quantum yields of CHDO above 300 nm

The photolysis of mono-deuterated formaldehyde, CHDO, is a critical process in the deuterium enrichment of stratospheric hydrogen formed from methane. In this work, a consistent description of the quantum yields of the molecular and radical channels of the CHDO photolysis is deduced from literature data.

Implementation of the ISORROPIA-lite aerosol thermodynamics model into the EMAC chemistry climate model (based on MESSy v2.55): implications for aerosol composition and acidity

Implementation of the ISORROPIA-lite aerosol thermodynamics model into the EMAC chemistry climate model (based on MESSy v2.55): implications for aerosol composition and acidity

This study explores the differences in performance and results by various versions of the ISORROPIA thermodynamic module implemented within the ECHAM/MESSy Atmospheric Chemistry (EMAC) model. Three different versions of the module were used, ISORROPIA II v1, ISORROPIA II v2.3, and ISORROPIA-lite.

A revised dry deposition scheme for land–atmosphere exchange of trace gases in ECHAM/MESSy v2.54

A revised dry deposition scheme for land–atmosphere exchange of trace gases in ECHAM/MESSy v2.54

Dry deposition to vegetation is a major sink of ground-level ozone and is responsible for about 20 % of the total tropospheric ozone loss. Its parameterization in atmospheric chemistry models represents a significant source of uncertainty for the global tropospheric ozone budget and might account for the mismatch with observations.

Parameterizations of US wildfire and prescribed fire emission ratios and emission factors based on FIREX-AQ aircraft measurements

Parameterizations of US wildfire and prescribed fire emission ratios and emission factors based on FIREX-AQ aircraft measurements

Extensive airborne measurements of non-methane organic gases (NMOGs), methane, nitrogen oxides, reduced nitrogen species, and aerosol emissions from US wild and prescribed fires were conducted during the 2019 NOAA/NASA Fire Influence on Regional to Global Environments and Air Quality campaign (FIREX-AQ).

Impact of temperature-dependent non-PAN peroxynitrate formation, RO2NO2, on nighttime atmospheric chemistry

Impact of temperature-dependent non-PAN peroxynitrate formation, RO2NO2, on nighttime atmospheric chemistry

The formation of peroxynitrates (RO2NO2) from the reaction of peroxy radicals (RO2) and nitrogen dioxide (NO2) and their subsequent redissociation are typically not included in chemical mechanisms.

Ozone pollution mitigation strategy informed by long-term trends of atmospheric oxidation capacity

Ozone pollution mitigation strategy informed by long-term trends of atmospheric oxidation capacity

Tropospheric ozone pollution is a critical air-quality concern in China. However, the most effective mitigation approach remains unclear, with prioritizing the reduction of volatile organic compounds or nitrogen oxides (NOX) currently still under debate.

New insights from the Jülich Ozone Sonde Intercomparison Experiment: calibration functions traceable to one ozone reference instrument

New insights from the Jülich Ozone Sonde Intercomparison Experiment: calibration functions traceable to one ozone reference instrument

Although in principle ECC (electrochemical concentration cell) ozonesondes are absolute measuring devices, in practice they have several “artefacts” which change over the course of a flight.

Intercomparison of Air Quality Models in a Megacity: Toward an Operational Ensemble Forecasting System for São Paulo

Intercomparison of Air Quality Models in a Megacity: Toward an Operational Ensemble Forecasting System for São Paulo

An intercomparison of four regional air quality models is performed in the tropical megacity of São Paulo with the perspective of developing a forecasting system based on a model ensemble. Modeled concentrations of the main regulated pollutants are compared with combined observations in the megacity center, after analyzing the spatial scale of representativeness of air monitoring stations.

Comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA: implications for atmospheric oxidative capacity

Comprehensive multiphase chlorine chemistry in the box model CAABA/MECCA: implications for atmospheric oxidative capacity

Tropospheric chlorine chemistry can strongly impact the atmospheric oxidation capacity and composition, especially in urban environments.

How non-equilibrium aerosol chemistry impacts particle acidity: the GMXe AERosol CHEMistry (GMXe–AERCHEM, v1.0) sub-submodel of MESSy

How non-equilibrium aerosol chemistry impacts particle acidity: the GMXe AERosol CHEMistry (GMXe–AERCHEM, v1.0) sub-submodel of MESSy

Aqueous-phase chemical processes in clouds, fog, and deliquescent aerosols are known to alter atmospheric composition and acidity significantly.

The importance of plant-water stress for predictions of ground-level ozone in a warm world

The importance of plant-water stress for predictions of ground-level ozone in a warm world

Evapotranspiration is important for Earth’s water and energy cycles as it strongly affects air temperature, cloud cover and precipitation.

Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals

Atmospheric photooxidation and ozonolysis of sabinene: reaction rate coefficients, product yields, and chemical budget of radicals

New publication in Atmospheric Physics and Chemistry about the oxidation of sabinene

Emulating lateral gravity wave propagation in a global chemistry–climate model (EMAC v2.55.2) through horizontal flux redistribution

Emulating lateral gravity wave propagation in a global chemistry–climate model (EMAC v2.55.2) through horizontal flux redistribution

The columnar approach of gravity wave (GW) parameterisations in weather and climate models has been identified as a potential reason for dynamical biases in middle-atmospheric dynamics. For example, GW momentum flux (GWMF) discrepancies between models and observations at 60∘ S arising through the lack of horizontal orographic GW propagation are suspected to cause deficiencies in representing the Antarctic polar vortex.

Measurement report: Carbonyl sulfide production during dimethyl sulfide oxidation in the atmospheric simulation chamber SAPHIR

Measurement report: Carbonyl sulfide production during dimethyl sulfide oxidation in the atmospheric simulation chamber SAPHIR

Carbonyl sulfide (OCS), the most abundant sulfur gas in the Earth's atmosphere, is a greenhouse gas, a precursor to stratospheric sulfate aerosol, and a proxy for terrestrial CO2 uptake. Estimates of important OCS sources and sinks still have significant uncertainties and the global budget is not considered closed.

Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.5.6-rc.1)

Development of a multiphase chemical mechanism to improve secondary organic aerosol formation in CAABA/MECCA (version 4.5.6-rc.1)

During the last decades, the impact of multiphase chemistry on secondary organic aerosol (SOA) has been demonstrated to be key in explaining lab experiments and field measurements.

Introduction to Atmospheric Simulation Chambers and Their Applications

Introduction to Atmospheric Simulation Chambers and Their Applications

Atmospheric simulation chambers have been deployed with various research goals for more than 80 years. In this chapter, an overview of the various applications, including emerging new applications, is given.

Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation

Comparison of isoprene chemical mechanisms under atmospheric night-time conditions in chamber experiments: evidence of hydroperoxy aldehydes and epoxy products from NO3 oxidation

The gas-phase reaction of isoprene with the nitrate radical (NO3) was investigated in experiments in the outdoor SAPHIR chamber under atmospherically relevant conditions specifically with respect to the chemical lifetime and fate of nitrato-organic peroxy radicals (RO2).

Upper-tropospheric slightly ice-subsaturated regions: frequency of occurrence and statistical evidence for the appearance of contrail cirrus

Upper-tropospheric slightly ice-subsaturated regions: frequency of occurrence and statistical evidence for the appearance of contrail cirrus

Microphysical, optical, and environmental properties of contrail cirrus and natural cirrus were investigated.

Electrochemical sensors on board a Zeppelin NT: in-flight evaluation of low-cost trace gas measurements

Electrochemical sensors on board a Zeppelin NT: in-flight evaluation of low-cost trace gas measurements

We report in situ measurements of air pollutant concentrations within the planetary boundary layer on board a Zeppelin NT in Germany. We highlight the in-flight evaluation of electrochemical sensors that were installed inside a hatch box located on the bottom of the Zeppelin. Results from this work emphasize the potential of these sensors for other in situ airborne applications, e.g., on board unmanned aerial vehicles (UAVs).

Air quality observations onboard commercial and targeted Zeppelin flights in Germany – a platform for high-resolution trace-gas and aerosol measurements within the planetary boundary layer

Air quality observations onboard commercial and targeted Zeppelin flights in Germany – a platform for high-resolution trace-gas and aerosol measurements within the planetary boundary layer

A Zeppelin airship was used as a platform for in situ measurements of greenhouse gases and short-lived air pollutants within the planetary boundary layer (PBL) in Germany.

Oxidation of low-molecular-weight organic compounds in cloud droplets: global impact on tropospheric oxidants

Oxidation of low-molecular-weight organic compounds in cloud droplets: global impact on tropospheric oxidants

In liquid cloud droplets, superoxide anion () is known to quickly consume ozone (O3(aq)), which is relatively insoluble. The significance of this reaction as a tropospheric O3 sink is sensitive to the abundance of and therefore to the production of its main precursor, the hydroperoxyl radical (HO2(aq)).

Oxidation of low-molecular-weight organic compounds in cloud droplets: development of the Jülich Aqueous-phase Mechanism of Organic Chemistry (JAMOC) in CAABA/MECCA (version 4.5.0)

Oxidation of low-molecular-weight organic compounds in cloud droplets: development of the Jülich Aqueous-phase Mechanism of Organic Chemistry (JAMOC) in CAABA/MECCA (version 4.5.0)

The Jülich Aqueous-phase Mechanism of Organic Chemistry (JAMOC) is developed and implemented in the Module Efficiently Calculating the Chemistry of the Atmosphere (MECCA; version 4.5.0). JAMOC is an explicit in-cloud oxidation scheme for oxygenated volatile organic compounds (OVOCs), suitable for global model applications.

The impact of organic pollutants from Indonesian peatland fires on the tropospheric and lower stratospheric composition

The impact of organic pollutants from Indonesian peatland fires on the tropospheric and lower stratospheric composition

The particularly strong dry season in Indonesia in 2015, caused by an exceptionally strong El Niño, led to severe peatland fires resulting in high volatile organic compound (VOC) biomass burning emissions.

Last Modified: 11.04.2024